Arsenide chloride

Arsenide chlorides or chloride arsenides are compounds containing anions composed of chloride (Cl⁻) and arsenide (As³⁻). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the arsenide bromides, arsenide iodides, phosphide chlorides, and antimonide chlorides.

List

formula	system	space group	unit cell Å	volume	density	comment	ref
Ca₃AsCl₃		Pm3m	a= 5.760				^[1]
Sr₂AsCl						dark violet	^[2]
Cd₈As₇Cl	cubic	P23	a=7.266, Z=1				^[3]
Hg_7.4As₄Cl₆	cubic	Pa3	a= 12.178, Z= 4				^[4]
(Hg₆As₄)(HgCl₆)Hg_0.5	cubic	Pa3	a=12.189 Z=4	1810.7	7.398	yellow; air stable; band gap 2.01	^[5]
(Hg₆As₄)[TiCl₆]Cl	cubic	Pa3	a = 1209.4				^[6]
[Hg₄As₂][ZrCl₆]	orthorhombic	Pbca	a=13.277 b=13.420 c=16.814 Z=8	2769.1	5.570	dark yellow	^[7]
[Hg₄As₂][HfCl₆]	orthorhombic	Pbca	a=13.273 b=13.413 c=16.809 Z=8	2992	5.964	orange	^[7]
(Hg₃AsS)(GaCl₄)	hexagonal	P6₃/mc	a =7.245, c =11.960 , Z = 2	543.6	5.622	light yellow	^[8]
Hg₃AsS₄Cl	hexagonal	P6₃mc	a = 7.431, c = 9.003 Z=2			yellow; air stable	^[9]
[Hg₆As₄](CuCl₃)₂	monoclinic	I2/a	a = 14.690, b = 9.1851, c = 20.285, β=92.170, Z=6				^[10]
(Hg_9.75As_5.5)(GaCl₄)₃	orthorhombic	Pmn2₁	a=22.567 b=12.146 c=12.983 Z=4	3559	5.604		^[11]
(Hg₆As₄)[MoCl₆]Cl	cubic	Pa3	a = 12.078				^[6]
[Hg₆As₄](AgCl₃)₂	monoclinic	I2/a	a = 14.690, b = 9.1851, c = 20.285, β = 93.17°, Z = 4				^[10]^[12]
(Hg₆As₄)(CdCl₆)Hg_0.5	cubic	Pa3	a=12.172 Z=4	1803.2	7.104	yellow; air stable; band gap 2.05	^[5]
[Hg₆As₄](InCl₆)Cl	cubic	Pa3	a = 12.109, Z = 4			dark red	^[13]
[Hg₆As₄Cl₃](SnCl₃)Hg_0.13	cubic	P2₁3	a=12.233 Z=4				^[14]
Hg₃As₂TlCl₃	orthorhombic	Pbcm	a = 6.292, b = 12.341 c = 12.248 Z=4			red	^[15]
Hg₆As₄BiCl₇	cubic	Pa3	a=12.178 Z=4				^[16]
[Hg₄As₂][UCl₆]	orthorhombic	Pbca	a=13.316 b=13.636 c=16.853 Z=8	3060.0	6.090	red	^[7]^[17]

References

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